1,2-Diazoles: Versatile Tectons for Metallosupramolecular Assemblies
نویسنده
چکیده
......................................................................................................................................... ii Abbreviations and Atom Colour Scheme .................................................................................... iii Chapter 1: Introduction ................................................................................................................ 1 1.1 Preamble and Scope.................................................................................................... 2 1.2 Supramolecular chemistry ......................................................................................... 2 1.3 Synthons in Metallosupramolecular chemistry ........................................................ 3 1.4 Discrete Assemblies..................................................................................................... 6 1.4.1 Applications of Discrete Supramolecular assemblies ................................... 7 1.5 Infinite Assemblies ...................................................................................................... 10 1.5.1 Coordination Polymers for Gas Sorption Applications ................................ 11 1.5.2 Topology ....................................................................................................... 15 1.6 Properties of 1,2-diazoles ........................................................................................... 20 1.6.1 Properties of Pyrazole and Pyrazole Derivatives ......................................... 20 1.6.2 Synthesis of Pyrazole Derivatives ................................................................. 21 1.6.3 Pyrazoles in Coordination Chemistry ........................................................... 22 1.6.4 Properties of Indazoles ................................................................................. 25 1.7 Present Study .............................................................................................................. 26 1.7.1 Methods of Compound Preparation and Data Collection ............................ 27 Chapter 2: Pyrazole-Carboxylate Mixed Ligand Systems ......................................................... 29 2.
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